Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp(3))−H bonds with alkynes

Transition metal-catalyzed enantioselective Sonogashira-type oxidative C(sp(3))—C(sp) coupling of unactivated C(sp(3))−H bonds with terminal alkynes has remained a prominent challenge. The difficulties mainly stem from the regiocontrol in unactivated C(sp(3))—H bond functionalization and the inhibit...

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Detalles Bibliográficos
Autores principales: Zhang, Zhen-Hua, Dong, Xiao-Yang, Du, Xuan-Yi, Gu, Qiang-Shuai, Li, Zhong-Liang, Liu, Xin-Yuan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6908613/
https://www.ncbi.nlm.nih.gov/pubmed/31831750
http://dx.doi.org/10.1038/s41467-019-13705-1

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6908613/
https://www.ncbi.nlm.nih.gov/pubmed/31831750
http://dx.doi.org/10.1038/s41467-019-13705-1

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