Cargando…

Copper-catalyzed enantioselective Sonogashira-type oxidative cross-coupling of unactivated C(sp(3))−H bonds with alkynes

Transition metal-catalyzed enantioselective Sonogashira-type oxidative C(sp(3))—C(sp) coupling of unactivated C(sp(3))−H bonds with terminal alkynes has remained a prominent challenge. The difficulties mainly stem from the regiocontrol in unactivated C(sp(3))—H bond functionalization and the inhibit...

Descripción completa

Detalles Bibliográficos
Autores principales:	Zhang, Zhen-Hua, Dong, Xiao-Yang, Du, Xuan-Yi, Gu, Qiang-Shuai, Li, Zhong-Liang, Liu, Xin-Yuan
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	Nature Publishing Group UK 2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6908613/ https://www.ncbi.nlm.nih.gov/pubmed/31831750 http://dx.doi.org/10.1038/s41467-019-13705-1

Ejemplares similares

Ni-catalyzed hydroarylation of alkynes with unactivated β-C(sp(2))−H bonds
por: Qi, Shao-Long, et al.
Publicado: (2022)

Enantioselective palladium/copper-catalyzed C–C σ-bond activation synergized with Sonogashira-type C(sp(3))–C(sp) cross-coupling alkynylation
por: Sun, Feng-Na, et al.
Publicado: (2019)

Artificial Metalloenzyme-Catalyzed Enantioselective Amidation via Nitrene Insertion in Unactivated C(sp(3))–H Bonds
por: Yu, Kun, et al.
Publicado: (2023)

Photo-induced copper-catalyzed alkynylation and amination of remote unactivated C(sp(3))-H bonds
por: Cao, Zhusong, et al.
Publicado: (2021)

Cobalt catalyzed carbonylation of unactivated C(sp(3))–H bonds
por: Barsu, Nagaraju, et al.
Publicado: (2017)

One-Pot Iridium Catalyzed C–H Borylation/Sonogashira Cross-Coupling: Access to Borylated Aryl Alkynes
por: Chotana, Ghayoor A., et al.
Publicado: (2020)

Functionalization of remote C(sp(3))-H bonds enabled by copper-catalyzed coupling of O-acyloximes with terminal alkynes
por: Li, Zhaodong, et al.
Publicado: (2020)

Palladium-catalyzed hydroboration reaction of unactivated alkynes with bis (pinacolato) diboron in water
por: Yang, Ming, et al.
Publicado: (2022)

Enantioselective Rhodium(III)-Catalyzed Markovnikov Hydroboration of Unactivated Terminal Alkenes
por: Smith, James R., et al.
Publicado: (2017)

Copper-catalyzed diamination of unactivated alkenes with hydroxylamines
por: Shen, Kun, et al.
Publicado: (2015)

Copper-catalyzed Sonogashira reactions: advances and perspectives since 2014
por: Arundhathi, Koduvarathodi Vadakkethil, et al.
Publicado: (2023)

Copper‐Catalyzed Aza‐Sonogashira Cross‐Coupling To Form Ynimines: Development and Application to the Synthesis of Heterocycles
por: Lavernhe, Rémi, et al.
Publicado: (2021)

Copper-catalyzed enantioselective diyne cyclization via C(sp(2))–O bond cleavage
por: Zhou, Ji-Jia, et al.
Publicado: (2023)

Nickel-catalyzed enantioselective allylic alkylation of lactones and lactams with unactivated allylic alcohols
por: Ngamnithiporn, Aurapat, et al.
Publicado: (2018)

Crossed Regio‐ and Enantioselective Iron‐Catalyzed [4+2]‐Cycloadditions of Unactivated Dienes
por: Braconi, Elena, et al.
Publicado: (2021)

Copper-Catalyzed Intermolecular Amidation and Imidation of Unactivated Alkanes
por: Tran, Ba L., et al.
Publicado: (2014)

Copper-free Sonogashira cross-coupling reactions: an overview
por: Mohajer, Fatemeh, et al.
Publicado: (2021)

Pyridine-enabled copper-promoted cross dehydrogenative coupling of C(sp(2))–H and unactivated C(sp(3))–H bonds
por: Wu, Xuesong, et al.
Publicado: (2015)

Dithiane-directed Rh(iii)-catalyzed amidation of unactivated C(sp(3))–H bonds
por: Shi, Heyao, et al.
Publicado: (2019)

Enantioselective alkylative cross-coupling of unactivated aromatic C–O electrophiles
por: Zhang, Zishuo, et al.
Publicado: (2022)

Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Palladium-Catalyzed Mizoroki–Heck and Copper-Free Sonogashira Coupling Reactions in Water Using Thermoresponsive Polymer Micelles
por: Suzuki, Noriyuki, et al.
Publicado: (2021)

Multimetallic catalysed radical oxidative C(sp(3))–H/C(sp)–H cross-coupling between unactivated alkanes and terminal alkynes
por: Tang, Shan, et al.
Publicado: (2016)

Bifunctional Iminophosphorane-Catalyzed Enantioselective Sulfa-Michael Addition to Unactivated α,β-Unsaturated Amides
por: Rozsar, Daniel, et al.
Publicado: (2022)

Structural Determinants of Alkyne Reactivity in Copper-Catalyzed Azide-Alkyne Cycloadditions
por: Zhang, Xiaoguang, et al.
Publicado: (2016)

Palladium-catalyzed ligand-promoted site-selective cyanomethylation of unactivated C(sp(3))–H bonds with acetonitrile
por: Liu, Yongbing, et al.
Publicado: (2016)

Palladium-catalyzed Sonogashira coupling reactions in γ-valerolactone-based ionic liquids
por: Orha, László, et al.
Publicado: (2019)

Enantioselective Csp3-Csp3 formation by nickel-catalyzed enantioconvergent cross-electrophile alkyl-alkyl coupling of unactivated alkyl halides
por: Zhao, Wen-Tao, et al.
Publicado: (2023)

Copper-catalyzed selective hydroamination reactions of alkynes
por: Shi, Shi-Liang, et al.
Publicado: (2014)

Au(I)/Au(III)-catalyzed Sonogashira-type reactions of functionalized terminal alkynes with arylboronic acids under mild conditions
por: Qian, Deyun, et al.
Publicado: (2011)

Enantioselective Copper-Catalyzed sp(2)/sp(3) Diborylation of 1-Chloro-1-Trifluoromethylalkenes
por: Fan, Zhenwei, et al.
Publicado: (2022)

Copper-catalyzed enantioselective arylalkynylation of alkenes
por: Lei, Guangyue, et al.
Publicado: (2020)

Photoredox-catalyzed aminofluorosulfonylation of unactivated olefins
por: Zhong, Tao, et al.
Publicado: (2021)

Nickel-catalyzed reductive coupling of homoenolates and their higher homologues with unactivated alkyl bromides
por: Lin, Tingzhi, et al.
Publicado: (2020)

Publisher Correction: Enantioselective Cu-catalyzed double hydroboration of alkynes to access chiral gem-diborylalkanes
por: Jin, Shengnan, et al.
Publicado: (2022)

Enantioselective Copper-Catalyzed Cyanation of Remote C(sp(3))-H Bonds Enabled by 1,5-Hydrogen Atom Transfer
por: Wang, Cheng-Yu, et al.
Publicado: (2019)

A General Acid‐Mediated Hydroaminomethylation of Unactivated Alkenes and Alkynes
por: Kaiser, Daniel, et al.
Publicado: (2019)

Copper‐Catalyzed Oxidative Cross‐Coupling of Electron‐Deficient Polyfluorophenylboronate Esters with Terminal Alkynes
por: Liu, Zhiqiang, et al.
Publicado: (2020)

Nickel-catalyzed reductive coupling of unactivated alkyl bromides and aliphatic aldehydes
por: Cruz, Cole L., et al.
Publicado: (2021)

Pd-catalyzed formal Mizoroki–Heck coupling of unactivated alkyl chlorides
por: Lee, Geun Seok, et al.
Publicado: (2021)

Cannot write session to /tmp/vufind_sessions/sess_9eobikjjrp6o1m4mimt0s3m2r6