Cargando…

Alkaline Earth Metal Template (Cross‐)Coupling Reactions with Hybrid Disila‐Crown Ether Analogues

Alkaline earth metal iodides were used as templates for the synthesis of novel silicon‐based ligands. Siloxane moieties were (cross‐)coupled and ion‐specific, silicon‐rich crown ether analogues were obtained. The reaction of 1,2,7,8‐tetrasila[12]crown‐4 (I) and 1,2‐disila[9]crown‐3 (II) with MgI(2)...

Descripción completa

Detalles Bibliográficos
Autores principales: Dankert, Fabian, Donsbach, Carsten, Rienmüller, Julia, Richter, Roman M., von Hänisch, Carsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916185/
https://www.ncbi.nlm.nih.gov/pubmed/31596978
http://dx.doi.org/10.1002/chem.201904209