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Bis‐Cyclometalated Indazole Chiral‐at‐Rhodium Catalyst for Asymmetric Photoredox Cyanoalkylations
A new class of bis‐cyclometalated rhodium(III) catalysts containing two inert cyclometalated 6‐tert‐butyl‐2‐phenyl‐2H‐indazole ligands and two labile acetonitriles is introduced. Single enantiomers (>99 % ee) were obtained through a chiral‐auxiliary‐mediated approach using a monofluorinated salic...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916287/ https://www.ncbi.nlm.nih.gov/pubmed/31541505 http://dx.doi.org/10.1002/chem.201903369 |