NHC‐Coordinated Diphosphene‐Stabilized Gold(I) Hydride and Its Reversible Conversion to Gold(I) Formate with CO(2)

An NHC‐coordinated diphosphene is employed as ligand for the synthesis of a hydrocarbon‐soluble monomeric Au(I) hydride, which readily adds CO(2) at room temperature yielding the corresponding Au(I) formate. The reversible reaction can be expedited by the addition of NHC, which induces β‐hydride shi...

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Detalles Bibliográficos
Autores principales: Dhara, Debabrata, Das, Shubhajit, Pati, Swapan K., Scheschkewitz, David, Chandrasekhar, Vadapalli, Jana, Anukul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916326/
https://www.ncbi.nlm.nih.gov/pubmed/31414524
http://dx.doi.org/10.1002/anie.201909798

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916326/
https://www.ncbi.nlm.nih.gov/pubmed/31414524
http://dx.doi.org/10.1002/anie.201909798

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