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X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases

[NiFe] hydrogenases are complex model enzymes for the reversible cleavage of dihydrogen (H(2)). However, structural determinants of efficient H(2) binding to their [NiFe] active site are not properly understood. Here, we present crystallographic and vibrational‐spectroscopic insights into the unexpl...

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Detalles Bibliográficos
Autores principales: Ilina, Yulia, Lorent, Christian, Katz, Sagie, Jeoung, Jae‐Hun, Shima, Seigo, Horch, Marius, Zebger, Ingo, Dobbek, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916344/
https://www.ncbi.nlm.nih.gov/pubmed/31591784
http://dx.doi.org/10.1002/anie.201908258