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X‐ray Crystallography and Vibrational Spectroscopy Reveal the Key Determinants of Biocatalytic Dihydrogen Cycling by [NiFe] Hydrogenases
[NiFe] hydrogenases are complex model enzymes for the reversible cleavage of dihydrogen (H(2)). However, structural determinants of efficient H(2) binding to their [NiFe] active site are not properly understood. Here, we present crystallographic and vibrational‐spectroscopic insights into the unexpl...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916344/ https://www.ncbi.nlm.nih.gov/pubmed/31591784 http://dx.doi.org/10.1002/anie.201908258 |