Mechanistic Divergence in the Hydrogenative Synthesis of Furans and Butenolides: Ruthenium Carbenes Formed by gem‐Hydrogenation or through Carbophilic Activation of Alkynes

Enynes with a tethered carbonyl substituent are converted into substituted furan derivatives upon hydrogenation using [Cp*RuCl](4) as the catalyst. Paradoxically, this transformation can occur along two distinct pathways, each of which proceeds via discrete pianostool ruthenium carbenes. In the firs...

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Detalles Bibliográficos
Autores principales: Peil, Sebastian, Fürstner, Alois
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916381/
https://www.ncbi.nlm.nih.gov/pubmed/31609498
http://dx.doi.org/10.1002/anie.201912161

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916381/
https://www.ncbi.nlm.nih.gov/pubmed/31609498
http://dx.doi.org/10.1002/anie.201912161

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