A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N−N Bond Cleavage

A novel method for the N−N bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes. The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d‐orbitals. This iron...

Descripción completa

Detalles Bibliográficos
Autores principales: Aghazada, Sadig, Miehlich, Matthias, Messelberger, Julian, Heinemann, Frank W., Munz, Dominik, Meyer, Karsten
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916540/
https://www.ncbi.nlm.nih.gov/pubmed/31529583
http://dx.doi.org/10.1002/anie.201910428

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916540/
https://www.ncbi.nlm.nih.gov/pubmed/31529583
http://dx.doi.org/10.1002/anie.201910428

Ejemplares similares