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A Terminal Iron Nitrilimine Complex: Accessing the Terminal Nitride through Diazo N−N Bond Cleavage

A novel method for the N−N bond cleavage of trimethylsilyl diazomethane is reported for the synthesis of terminal nitride complexes. The lithium salt of trimethylsilyl diazomethane was used to generate a rare terminal nitrilimine transition metal complex with partially occupied d‐orbitals. This iron...

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Detalles Bibliográficos
Autores principales:	Aghazada, Sadig, Miehlich, Matthias, Messelberger, Julian, Heinemann, Frank W., Munz, Dominik, Meyer, Karsten
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6916540/ https://www.ncbi.nlm.nih.gov/pubmed/31529583 http://dx.doi.org/10.1002/anie.201910428

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