Helix-Sense-Selective Polymerization of 3,5-bis(hydroxymethyl)phenylacetylene Rigidly Bearing Galvinoxyl Residues and Their Chiroptical Properties

Four kinds of newly synthesized achiral phenylacetylenes bearing a phenylhydrogalvinoxyl residue at 4-position were polymerized by using a chiral rhodium catalyst system, [Rh(nbd)B(C(6)H(5))(4)] or [Rh(nbd)Cl](2) catalysts in the presence of chiral (R)-(+)- or (S)-(–)-1-phenylethylamine ((R)- or (S)...

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Detalles Bibliográficos
Autores principales: Shi, Zhichun, Wang, Jianjun, Teraguchi, Masahiro, Aoki, Toshiki, Kaneko, Takashi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918253/
https://www.ncbi.nlm.nih.gov/pubmed/31766269
http://dx.doi.org/10.3390/polym11111877

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918253/
https://www.ncbi.nlm.nih.gov/pubmed/31766269
http://dx.doi.org/10.3390/polym11111877

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