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Helix-Sense-Selective Polymerization of 3,5-bis(hydroxymethyl)phenylacetylene Rigidly Bearing Galvinoxyl Residues and Their Chiroptical Properties

Four kinds of newly synthesized achiral phenylacetylenes bearing a phenylhydrogalvinoxyl residue at 4-position were polymerized by using a chiral rhodium catalyst system, [Rh(nbd)B(C(6)H(5))(4)] or [Rh(nbd)Cl](2) catalysts in the presence of chiral (R)-(+)- or (S)-(–)-1-phenylethylamine ((R)- or (S)...

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Detalles Bibliográficos
Autores principales:	Shi, Zhichun, Wang, Jianjun, Teraguchi, Masahiro, Aoki, Toshiki, Kaneko, Takashi
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	MDPI 2019
Materias:	Article
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6918253/ https://www.ncbi.nlm.nih.gov/pubmed/31766269 http://dx.doi.org/10.3390/polym11111877

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