Proton Acceptor near the Active Site Lowers Dramatically the O–O Bond Formation Energy Barrier in Photocatalytic Water Splitting

[Image: see text] The O–O bond formation process via water nucleophilic attack represents a thermodynamic and kinetic bottleneck in photocatalytic water oxidation because of the considerably high activation free energy barrier. It is therefore of fundamental significance and yet challenging to find...

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Detalles Bibliográficos
Autores principales: Shao, Yang, de Groot, Huub J.M., Buda, Francesco
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6926955/
https://www.ncbi.nlm.nih.gov/pubmed/31763842
http://dx.doi.org/10.1021/acs.jpclett.9b02914

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6926955/
https://www.ncbi.nlm.nih.gov/pubmed/31763842
http://dx.doi.org/10.1021/acs.jpclett.9b02914

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