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Isolation of a Halogen-Bonded Complex Formed between Methane and Chlorine Monofluoride and Characterisation by Rotational Spectroscopy and Ab Initio Calculations

A halogen-bonded complex formed between methane and chlorine monofluoride has been isolated in the gas phase before the reaction between the components and has been characterised through its rotational spectrum, which is of the symmetric-top type but only exhibits K = 0 type transitions at the low e...

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Detalles Bibliográficos
Autores principales: Legon, Anthony C., Lister, David G., Holloway, John H., Mani, Devendra, Arunan, Elangannan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6930488/
https://www.ncbi.nlm.nih.gov/pubmed/31766716
http://dx.doi.org/10.3390/molecules24234257