2-Unsubstituted Imidazole N-Oxides as Novel Precursors of Chiral 3-Alkoxyimidazol-2-ylidenes Derived from trans-1,2-Diaminocyclohexane and Other Chiral Amino Compounds †

‘Desymmetrization’ of trans-1,2-diaminocyclohexane by treatment with α,ω-dihalogenated alkylation reagents leads to mono-NH(2) derivatives (‘primary-tertiary diamines’). Upon reaction with formaldehyde, these products formed monomeric formaldimines. Subsequently, reactions of the formaldimines with...

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Detalles Bibliográficos
Autores principales: Mlostoń, Grzegorz, Celeda, Małgorzata, Jasiński, Marcin, Urbaniak, Katarzyna, Boratyński, Przemysław J., Schreiner, Peter R., Heimgartner, Heinz
Formato: Online Artículo Texto
Lenguaje:English
Publicado: MDPI 2019
Materias:
Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6930529/
https://www.ncbi.nlm.nih.gov/pubmed/31810181
http://dx.doi.org/10.3390/molecules24234398

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6930529/
https://www.ncbi.nlm.nih.gov/pubmed/31810181
http://dx.doi.org/10.3390/molecules24234398

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