Chiral Autoamplification Meets Dynamic Chirality Control to Suggest Nonautocatalytic Chemical Model of Prebiotic Chirality Amplification

Oxidative kinetic resolution of 1-phenylethanol in the presence of manganese complexes, bearing conformationally nonrigid achiral bis-amine-bis-pyridine ligands, in the absence of any exogenous chiral additives, is reported. The only driving force for the chiral discrimination is the small initial e...

Descripción completa

Detalles Bibliográficos
Autores principales: Talsi, Evgenii P., Bryliakova, Anna A., Ottenbacher, Roman V., Rybalova, Tatyana V., Bryliakov, Konstantin P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2019
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946252/
https://www.ncbi.nlm.nih.gov/pubmed/31922134
http://dx.doi.org/10.34133/2019/4756025

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946252/
https://www.ncbi.nlm.nih.gov/pubmed/31922134
http://dx.doi.org/10.34133/2019/4756025

Ejemplares similares