Chiral Autoamplification Meets Dynamic Chirality Control to Suggest Nonautocatalytic Chemical Model of Prebiotic Chirality Amplification

Oxidative kinetic resolution of 1-phenylethanol in the presence of manganese complexes, bearing conformationally nonrigid achiral bis-amine-bis-pyridine ligands, in the absence of any exogenous chiral additives, is reported. The only driving force for the chiral discrimination is the small initial e...

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Detalles Bibliográficos
Autores principales: Talsi, Evgenii P., Bryliakova, Anna A., Ottenbacher, Roman V., Rybalova, Tatyana V., Bryliakov, Konstantin P.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2019
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946252/
https://www.ncbi.nlm.nih.gov/pubmed/31922134
http://dx.doi.org/10.34133/2019/4756025

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