Fusing Carbocycles of Inequivalent Ring Size to a Bis(imino)pyridine-Iron Ethylene Polymerization Catalyst: Distinctive Effects on Activity, PE Molecular Weight, and Dispersity

The 4,6-bis(arylimino)-1,2,3,7,8,9,10-heptahydrocyclohepta[b]quinoline-iron(II) chlorides (aryl = 2,6-Me(2)C(6)H(3)Fe1; 2,6-Et(2)C(6)H(3)Fe2; 2,6-i-Pr(2)C(6)H(3)Fe3; 2,4,6-Me(3)C(6)H(2)Fe4; and 2,6-Et(2)-4-Me(2)C(6)H(2)Fe5) have been prepared in good yield by a straightforward one-pot reaction of 2,...

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Detalles Bibliográficos
Autores principales: Wang, Zheng, Solan, Gregory A., Ma, Yanping, Liu, Qingbin, Liang, Tongling, Sun, Wen-Hua
Formato: Online Artículo Texto
Lenguaje:English
Publicado: AAAS 2019
Materias:
Research Article
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946285/
https://www.ncbi.nlm.nih.gov/pubmed/31922146
http://dx.doi.org/10.34133/2019/9426063

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6946285/
https://www.ncbi.nlm.nih.gov/pubmed/31922146
http://dx.doi.org/10.34133/2019/9426063

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