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Strong inverse kinetic isotope effect observed in ammonia charge exchange reactions
Isotopic substitution has long been used to understand the detailed mechanisms of chemical reactions; normally the substitution of hydrogen by deuterium leads to a slower reaction. Here, we report our findings on the charge transfer collisions of cold [Formula: see text] ions and two isotopologues o...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6954264/ https://www.ncbi.nlm.nih.gov/pubmed/31924778 http://dx.doi.org/10.1038/s41467-019-13976-8 |