Ligand Redox Noninnocence in [Co(III)(TAML)](0/–) Complexes Affects Nitrene Formation

[Image: see text] The redox noninnocence of the TAML scaffold in cobalt-TAML (tetra-amido macrocyclic ligand) complexes has been under debate since 2006. In this work, we demonstrate with a variety of spectroscopic measurements that the TAML backbone in the anionic complex [Co(III)(TAML(red))](–) is...

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Detalles Bibliográficos
Autores principales: van Leest, Nicolaas P., Tepaske, Martijn A., Oudsen, Jean-Pierre H., Venderbosch, Bas, Rietdijk, Niels R., Siegler, Maxime A., Tromp, Moniek, van der Vlugt, Jarl Ivar, de Bruin, Bas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2019
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6956250/
https://www.ncbi.nlm.nih.gov/pubmed/31846578
http://dx.doi.org/10.1021/jacs.9b11715

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6956250/
https://www.ncbi.nlm.nih.gov/pubmed/31846578
http://dx.doi.org/10.1021/jacs.9b11715

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