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A hierarchically assembled 88-nuclei silver-thiacalix[4]arene nanocluster
Thiacalix[4]arenes as a family of promising ligands have been widely used to construct polynuclear metal clusters, but scarcely employed in silver nanoclusters. Herein, an anion-templated Ag(88) nanocluster (SD/Ag88a) built from p-tert-butylthiacalix[4]arene (H(4)TC4A) is reported. Single-crystal X-...
Autores principales: | , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6965622/ https://www.ncbi.nlm.nih.gov/pubmed/31949133 http://dx.doi.org/10.1038/s41467-019-13682-5 |