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Quantification of energy of activation to supramolecular nanofibre formation reveals enthalpic and entropic effects and morphological consequence

We show a self-assembly process leading to fibres from a system that starts far from equilibrium because of fast solvent – anti-solvent mixing and analyse the activation energies associated with the aggregation. It is in some ways reminiscent of diverse natural fibrous materials that have kinetic be...

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Detalles Bibliográficos
Autores principales: Samperi, Mario, Pérez-García, Lluïsa, Amabilino, David B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968731/
https://www.ncbi.nlm.nih.gov/pubmed/32015821
http://dx.doi.org/10.1039/c9sc03280k