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Quantification of energy of activation to supramolecular nanofibre formation reveals enthalpic and entropic effects and morphological consequence
We show a self-assembly process leading to fibres from a system that starts far from equilibrium because of fast solvent – anti-solvent mixing and analyse the activation energies associated with the aggregation. It is in some ways reminiscent of diverse natural fibrous materials that have kinetic be...
Autores principales: | Samperi, Mario, Pérez-García, Lluïsa, Amabilino, David B. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Royal Society of Chemistry
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968731/ https://www.ncbi.nlm.nih.gov/pubmed/32015821 http://dx.doi.org/10.1039/c9sc03280k |
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