Installation of internal electric fields by non-redox active cations in transition metal complexes

Local electric fields contribute to the high selectivity and catalytic activity in enzyme active sites and confined reaction centers in zeolites by modifying the relative energy of transition states, intermediates and/or products. Proximal charged functionalities can generate equivalent internal ele...

Descripción completa

Detalles Bibliográficos
Autores principales: Kang, Kevin, Fuller, Jack, Reath, Alexander H., Ziller, Joseph W., Alexandrova, Anastassia N., Yang, Jenny Y.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968733/
https://www.ncbi.nlm.nih.gov/pubmed/32015820
http://dx.doi.org/10.1039/c9sc02870f

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968733/
https://www.ncbi.nlm.nih.gov/pubmed/32015820
http://dx.doi.org/10.1039/c9sc02870f

Ejemplares similares