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Photochemical ring expansion reactions: synthesis of tetrahydrofuran derivatives and mechanism studies

The reaction mechanism of oxygen and sulfur ylide mediated rearrangements is even today a matter of debate. In this report, we describe ring expansion reactions of oxetane and thietane heterocycles that allow probing the underlying reaction mechanism under metal-free, photochemical conditions. This...

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Detalles Bibliográficos
Autores principales: Jana, Sripati, Yang, Zhen, Pei, Chao, Xu, Xinfang, Koenigs, Rene M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6968735/
https://www.ncbi.nlm.nih.gov/pubmed/32015819
http://dx.doi.org/10.1039/c9sc04069b