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Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms

Despite their importance as mechanistic models for heterogeneous Haber Bosch ammonia synthesis from dinitrogen and dihydrogen, homogeneous molecular terminal metal-nitrides are notoriously unreactive towards dihydrogen, and only a few electron-rich, low-coordinate variants demonstrate any hydrogenol...

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Detalles Bibliográficos
Autores principales: Chatelain, Lucile, Louyriac, Elisa, Douair, Iskander, Lu, Erli, Tuna, Floriana, Wooles, Ashley J., Gardner, Benedict M., Maron, Laurent, Liddle, Stephen T.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Nature Publishing Group UK 2020
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6969212/
https://www.ncbi.nlm.nih.gov/pubmed/31953390
http://dx.doi.org/10.1038/s41467-019-14221-y