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Terminal uranium(V)-nitride hydrogenations involving direct addition or Frustrated Lewis Pair mechanisms
Despite their importance as mechanistic models for heterogeneous Haber Bosch ammonia synthesis from dinitrogen and dihydrogen, homogeneous molecular terminal metal-nitrides are notoriously unreactive towards dihydrogen, and only a few electron-rich, low-coordinate variants demonstrate any hydrogenol...
Autores principales: | , , , , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Nature Publishing Group UK
2020
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6969212/ https://www.ncbi.nlm.nih.gov/pubmed/31953390 http://dx.doi.org/10.1038/s41467-019-14221-y |