Copper‐Catalyzed Triboration: Straightforward, Atom‐Economical Synthesis of 1,1,1‐Triborylalkanes from Terminal Alkynes and HBpin

A convenient and efficient one‐step synthesis of 1,1,1‐triborylalkanes was achieved via sequential dehydrogenative borylation and double hydroborations of terminal alkynes with HBpin (HBpin=pinacolborane) catalyzed by inexpensive and readily available Cu(OAc)(2). This process proceeds under mild con...

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Detalles Bibliográficos
Autores principales: Liu, Xiaocui, Ming, Wenbo, Zhang, Yixiao, Friedrich, Alexandra, Marder, Todd B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972527/
https://www.ncbi.nlm.nih.gov/pubmed/31490606
http://dx.doi.org/10.1002/anie.201909376

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972527/
https://www.ncbi.nlm.nih.gov/pubmed/31490606
http://dx.doi.org/10.1002/anie.201909376

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