Alpha‐Carbonic Acid Revisited: Carbonic Acid Monomethyl Ester as a Solid and its Conformational Isomerism in the Gas Phase

In this work, earlier studies reporting α‐H(2)CO(3) are revised. The cryo‐technique pioneered by Hage, Hallbrucker, and Mayer (HHM) is adapted to supposedly prepare carbonic acid from KHCO(3). In methanolic solution, methylation of the salt is found, which upon acidification transforms to the monome...

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Detalles Bibliográficos
Autores principales: Köck, Eva‐Maria, Bernard, Jürgen, Podewitz, Maren, Dinu, Dennis F., Huber, Roland G., Liedl, Klaus R., Grothe, Hinrich, Bertel, Erminald, Schlögl, Robert, Loerting, Thomas
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Full Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972543/
https://www.ncbi.nlm.nih.gov/pubmed/31593601
http://dx.doi.org/10.1002/chem.201904142

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972543/
https://www.ncbi.nlm.nih.gov/pubmed/31593601
http://dx.doi.org/10.1002/chem.201904142

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