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Alpha‐Carbonic Acid Revisited: Carbonic Acid Monomethyl Ester as a Solid and its Conformational Isomerism in the Gas Phase
In this work, earlier studies reporting α‐H(2)CO(3) are revised. The cryo‐technique pioneered by Hage, Hallbrucker, and Mayer (HHM) is adapted to supposedly prepare carbonic acid from KHCO(3). In methanolic solution, methylation of the salt is found, which upon acidification transforms to the monome...
| Autores principales: | , , , , , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
John Wiley and Sons Inc.
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972543/ https://www.ncbi.nlm.nih.gov/pubmed/31593601 http://dx.doi.org/10.1002/chem.201904142 |