Acyl Migration versus Epoxidation in Gold Catalysis: Facile, Switchable, and Atom‐Economic Synthesis of Acylindoles and Quinoline Derivatives

We report a switchable synthesis of acylindoles and quinoline derivatives via gold‐catalyzed annulations of anthranils and ynamides. α‐Imino gold carbenes, generated in situ from anthranils and an N,O‐coordinated gold(III) catalyst, undergo electrophilic attack to the aryl π‐bond, followed by unexpe...

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Detalles Bibliográficos
Autores principales: Tian, Xianhai, Song, Lina, Farshadfar, Kaveh, Rudolph, Matthias, Rominger, Frank, Oeser, Thomas, Ariafard, Alireza, Hashmi, A. Stephen K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Research Articles
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972584/
https://www.ncbi.nlm.nih.gov/pubmed/31622542
http://dx.doi.org/10.1002/anie.201912334

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972584/
https://www.ncbi.nlm.nih.gov/pubmed/31622542
http://dx.doi.org/10.1002/anie.201912334

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