Regioselective Hydrosilylation of Olefins Catalyzed by a Molecular Calcium Hydride Cation

Chemo‐ and regioselectivity are often difficult to control during olefin hydrosilylation catalyzed by d‐ and f‐block metal complexes. The cationic hydride of calcium [CaH](+) stabilized by an NNNN macrocycle was found to catalyze the regioselective hydrosilylation of aliphatic olefins to give anti‐M...

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Detalles Bibliográficos
Autores principales: Schuhknecht, Danny, Spaniol, Thomas P., Maron, Laurent, Okuda, Jun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972613/
https://www.ncbi.nlm.nih.gov/pubmed/31609062
http://dx.doi.org/10.1002/anie.201909585

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972613/
https://www.ncbi.nlm.nih.gov/pubmed/31609062
http://dx.doi.org/10.1002/anie.201909585

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