trans‐Selective Insertional Dihydroboration of a cis‐Diborene: Synthesis of Linear sp(3)‐sp(2)‐sp(3)‐Triboranes and Subsequent Cationization

The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans‐dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the B=B bond. The aryltriborane derivatives undergo reversible photoisomerization to the cis‐1,2‐μ‐H‐3‐hydro...

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Detalles Bibliográficos
Autores principales: Schmidt, Uwe, Werner, Luis, Arrowsmith, Merle, Deissenberger, Andrea, Hermann, Alexander, Hofmann, Alexander, Ullrich, Stefan, Mattock, James D., Vargas, Alfredo, Braunschweig, Holger
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972689/
https://www.ncbi.nlm.nih.gov/pubmed/31621993
http://dx.doi.org/10.1002/anie.201911645

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972689/
https://www.ncbi.nlm.nih.gov/pubmed/31621993
http://dx.doi.org/10.1002/anie.201911645

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