Cargando…

trans‐Selective Insertional Dihydroboration of a cis‐Diborene: Synthesis of Linear sp(3)‐sp(2)‐sp(3)‐Triboranes and Subsequent Cationization

The reaction of aryl‐ and amino(dihydro)boranes with dibora[2]ferrocenophane 1 leads to the formation 1,3‐trans‐dihydrotriboranes by formal hydrogenation and insertion of a borylene unit into the B=B bond. The aryltriborane derivatives undergo reversible photoisomerization to the cis‐1,2‐μ‐H‐3‐hydro...

Descripción completa

Detalles Bibliográficos
Autores principales:	Schmidt, Uwe, Werner, Luis, Arrowsmith, Merle, Deissenberger, Andrea, Hermann, Alexander, Hofmann, Alexander, Ullrich, Stefan, Mattock, James D., Vargas, Alfredo, Braunschweig, Holger
Formato:	Online Artículo Texto
Lenguaje:	English
Publicado:	John Wiley and Sons Inc. 2019
Materias:	Communications
Acceso en línea:	https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972689/ https://www.ncbi.nlm.nih.gov/pubmed/31621993 http://dx.doi.org/10.1002/anie.201911645

Ejemplares similares

Synthesis and hydrogenation of polycyclic aromatic hydrocarbon-substituted diborenes via uncatalysed hydrogenative B–C bond cleavage
por: Okorn, Alexander, et al.
Publicado: (2022)

Isolation of diborenes and their 90°-twisted diradical congeners
por: Böhnke, Julian, et al.
Publicado: (2018)

Can a Wanzlick-like equilibrium exist between dicoordinate borylenes and diborenes?
por: Fantuzzi, Felipe, et al.
Publicado: (2022)

Reactions of diborenes with terminal alkynes: mechanisms of ligand-controlled anti-selective hydroalkynylation, cycloaddition and C[triple bond, length as m-dash]C triple bond scission
por: Englert, Lukas, et al.
Publicado: (2021)

Site-Selective C(sp(3))–C(sp)/C(sp(3))–C(sp(2)) Cross-Coupling Reactions Using Frustrated Lewis Pairs
por: Dasgupta, Ayan, et al.
Publicado: (2021)

Specificity protein (Sp) transcription factors Sp1, Sp3 and Sp4 are non-oncogene addiction genes in cancer cells
por: Hedrick, Erik, et al.
Publicado: (2016)

Recent Advances in C(sp(3))–C(sp(3)) and C(sp(3))–C(sp(2)) Bond Formation through Cathodic Reactions: Reductive and Convergent Paired Electrolyses
por: Claraz, Aurélie, et al.
Publicado: (2021)

An Sp1/Sp3 Binding Polymorphism Confers Methylation Protection
por: Boumber, Yanis A., et al.
Publicado: (2008)

Practical Catalytic Cleavage of C(sp(3))−C(sp(3)) Bonds in Amines
por: Li, Wu, et al.
Publicado: (2019)

Spin-state crossover in photo-catalyzed nitrile dihydroboration via Mn-thiolate cooperation
por: Elsby, Matthew R., et al.
Publicado: (2022)

Sp1 and Sp3 regulate basal transcription of the human APOBEC3G gene
por: Muckenfuss, Heide, et al.
Publicado: (2007)

An Unsymmetrical, Cyclic Diborene Based on a Chelating CAAC Ligand and its Small‐Molecule Activation and Rearrangement Chemistry
por: Lu, Wei, et al.
Publicado: (2021)

Physiological TLR5 expression in the intestine is regulated by differential DNA binding of Sp1/Sp3 through simultaneous Sp1 dephosphorylation and Sp3 phosphorylation by two different PKC isoforms
por: Thakur, Bhupesh Kumar, et al.
Publicado: (2016)

Predictive Value of Sp1/Sp3/FLIP Signature for Prostate Cancer Recurrence
por: Bedolla, Roble G., et al.
Publicado: (2012)

Oxidative coupling of sp(2) and sp(3) carbon–hydrogen bonds to construct dihydrobenzofurans
por: Shi, Jiang-Ling, et al.
Publicado: (2017)

Robust hematopoietic specification requires the ubiquitous Sp1 and Sp3 transcription factors
por: Gilmour, Jane, et al.
Publicado: (2019)

Mixed sp(2)–sp(3) Nanocarbon Materials: A Status Quo Review
por: Vejpravová, Jana
Publicado: (2021)

Electrochemical Benzylic C(sp(3))–H Acyloxylation
por: Atkins, Alexander P., et al.
Publicado: (2022)

Controlled Synthesis of Oligomers Containing Main‐Chain B(sp(2))‐B(sp(2)) Bonds
por: Schorr, Fabian, et al.
Publicado: (2021)

Draft Genome Sequences of Five Neonatal Meningitis-Causing Escherichia coli Isolates (SP-4, SP-5, SP-13, SP-46, and SP-65)
por: Xu, Aixia, et al.
Publicado: (2018)

Recent advances in Cu-catalyzed C(sp(3))–Si and C(sp(3))–B bond formation
por: Takale, Balaram S, et al.
Publicado: (2020)

Actinobacteria Associated with the Marine Sponges Cinachyra sp., Petrosia sp., and Ulosa sp. and Their Culturability
por: Khan, Shams Tabrez, et al.
Publicado: (2012)

Alterations of Bacteroides sp., Neisseria sp., Actinomyces sp., and Streptococcus sp. populations in the oropharyngeal microbiome are associated with liver cirrhosis and pneumonia
por: Lu, Haifeng, et al.
Publicado: (2015)

Silencing the SpMPK1, SpMPK2, and SpMPK3 Genes in Tomato Reduces Abscisic Acid—Mediated Drought Tolerance
por: Li, Cui, et al.
Publicado: (2013)

Alkaliphilus flagellatus sp. nov., Butyricicoccus intestinisimiae sp. nov., Clostridium mobile sp. nov., Clostridium simiarum sp. nov., Dysosmobacter acutus sp. nov., Paenibacillus brevis sp. nov., Peptoniphilus ovalis sp. nov. and Tissierella simiarum sp. nov., isolated from monkey faeces
por: Li, Dan-Hua, et al.
Publicado: (2022)

Ligand-Promoted Alkylation of C(sp(3))–H and C(sp(2))–H Bonds
por: Zhu, Ru-Yi, et al.
Publicado: (2014)

Chemoselective Activation of sp(3) vs sp(2) C–H Bonds with Pd(II)
por: Curto, John M., et al.
Publicado: (2014)

Pd-catalyzed sp–sp(3) cross-coupling of benzyl bromides using lithium acetylides
por: Mondal, Anirban, et al.
Publicado: (2021)

Enantioselective Copper-Catalyzed sp(2)/sp(3) Diborylation of 1-Chloro-1-Trifluoromethylalkenes
por: Fan, Zhenwei, et al.
Publicado: (2022)

Shock-formed carbon materials with intergrown sp(3)- and sp(2)-bonded nanostructured units
por: Németh, Péter, et al.
Publicado: (2022)

Endothelial Sp1/Sp3 are essential to the effect of captopril on blood pressure in male mice
por: Lu, Hanlin, et al.
Publicado: (2023)

Different Antifungal Activity of Anabaena sp., Ecklonia sp., and Jania sp. against Botrytis cinerea
por: Righini, Hillary, et al.
Publicado: (2019)

Electrocatalytic Activation of Donor–Acceptor Cyclopropanes and Cyclobutanes: An Alternative C(sp(3))−C(sp(3)) Cleavage Mode
por: Kolb, Simon, et al.
Publicado: (2021)

Electrochemical Nickel-Catalyzed C(sp(3))–C(sp(3)) Cross-Coupling of Alkyl Halides with Alkyl Tosylates
por: Ibrahim, Malek Y. S., et al.
Publicado: (2023)

Yersinia artesiana sp. nov., Yersinia proxima sp. nov., Yersinia alsatica sp. nov., Yersina vastinensis sp. nov., Yersinia thracica sp. nov. and Yersinia occitanica sp. nov., isolated from humans and animals
por: Le Guern, Anne-Sophie, et al.
Publicado: (2020)

Description of ‘Bacillus dakarensis’ sp. nov., ‘Bacillus sinesaloumensis’ sp. nov., ‘Gracilibacillus timonensis’ sp. nov., ‘Halobacillus massiliensis’ sp. nov., ‘Lentibacillus massiliensis’ sp. nov., ‘Oceanobacillus senegalensis’ sp. nov., ‘Oceanobacillus timonensis’ sp. nov., ‘Virgibacillus dakarensis’ sp. nov. and ‘Virgibacillus marseillensis’ sp. nov., nine halophilic new species isolated from human stool
por: Senghor, B., et al.
Publicado: (2017)

Cationic Phosphorus Compounds Based on a Bis(1-piperidinyl)-Substituted Carbodiphosphorane: Syntheses, Structures, and C(sp(3))–H Activation
por: Kroll, Alexander, et al.
Publicado: (2020)

Emerging Applications of Chlorella sp. and Spirulina (Arthrospira) sp.
por: Abreu, Ana P., et al.
Publicado: (2023)

Enantiospecific sp(2)–sp(3) Coupling of ortho‐ and para‐Phenols with Secondary and Tertiary Boronic Esters
por: Wilson, Claire M., et al.
Publicado: (2017)

Copper-promoted site-selective carbonylation of sp(3) and sp(2) C–H bonds with nitromethane
por: Wu, Xuesong, et al.
Publicado: (2016)

Cannot write session to /tmp/vufind_sessions/sess_apuqis56844kccqqf3iho1qusf