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[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide

The activation of white phosphorus (P(4)) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P(5) ligan...

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Detalles Bibliográficos
Autores principales: Hoidn, Christian M., Maier, Thomas M., Trabitsch, Karolina, Weigand, Jan J., Wolf, Robert
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972699/
https://www.ncbi.nlm.nih.gov/pubmed/31573718
http://dx.doi.org/10.1002/anie.201908744