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[3+2] Fragmentation of a Pentaphosphido Ligand by Cyanide
The activation of white phosphorus (P(4)) by transition‐metal complexes has been studied for several decades, but the functionalization and release of the resulting (organo)phosphorus ligands has rarely been achieved. Herein we describe the formation of rare diphosphan‐1‐ide anions from a P(5) ligan...
Autores principales: | Hoidn, Christian M., Maier, Thomas M., Trabitsch, Karolina, Weigand, Jan J., Wolf, Robert |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6972699/ https://www.ncbi.nlm.nih.gov/pubmed/31573718 http://dx.doi.org/10.1002/anie.201908744 |
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