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Direct Identification of Acetaldehyde Formation and Characterization of the Active Site in the [VPO(4)](.+)/C(2)H(4) Couple by Gas‐Phase Vibrational Spectroscopy

The gas‐phase reaction of the heteronuclear oxide cluster [VPO(4)](.+) with C(2)H(4) is studied under multiple collision conditions at 150 K using cryogenic ion‐trap vibrational spectroscopy combined with electronic structure calculations. The exclusive formation of acetaldehyde is directly identifi...

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Detalles Bibliográficos
Autores principales: Li, Ya‐Ke, Debnath, Sreekanta, Schlangen, Maria, Schöllkopf, Wieland, Asmis, Knut R., Schwarz, Helmut
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973009/
https://www.ncbi.nlm.nih.gov/pubmed/31637840
http://dx.doi.org/10.1002/anie.201911040