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Direct Identification of Acetaldehyde Formation and Characterization of the Active Site in the [VPO(4)](.+)/C(2)H(4) Couple by Gas‐Phase Vibrational Spectroscopy
The gas‐phase reaction of the heteronuclear oxide cluster [VPO(4)](.+) with C(2)H(4) is studied under multiple collision conditions at 150 K using cryogenic ion‐trap vibrational spectroscopy combined with electronic structure calculations. The exclusive formation of acetaldehyde is directly identifi...
Autores principales: | , , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
John Wiley and Sons Inc.
2019
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973009/ https://www.ncbi.nlm.nih.gov/pubmed/31637840 http://dx.doi.org/10.1002/anie.201911040 |