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Reactions of Bromine Fluoride Dioxide, BrO(2)F, for the Generation of the Mixed‐Valent Bromine Oxygen Cations Br(3)O(4) (+) and Br(3)O(6) (+)
A reliable synthesis of unstable and highly reactive BrO(2)F is reported. This compound can be converted into BrO(2) (+)SbF(6) (−), BrO(2) (+)AsF(6) (−) (,) and BrO(2) (+)AsF(6) (−)⋅2 BrO(2)F. The latter decomposes into mixed‐valent Br(3)O(4)⋅Br(2) (+)AsF(6) (−) with five‐, three‐, one‐, and zero‐va...
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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John Wiley and Sons Inc.
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973041/ https://www.ncbi.nlm.nih.gov/pubmed/31622009 http://dx.doi.org/10.1002/anie.201912271 |