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Cubane Electrochemistry: Direct Conversion of Cubane Carboxylic Acids to Alkoxy Cubanes Using the Hofer–Moest Reaction under Flow Conditions

The highly strained cubane system is of great interest as a scaffold and rigid linker in both pharmaceutical and materials chemistry. The first electrochemical functionalisation of cubane by oxidative decarboxylative ether formation (Hofer–Moest reaction) was demonstrated. The mild conditions are co...

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Detalles Bibliográficos
Autores principales: Collin, Diego E., Folgueiras‐Amador, Ana A., Pletcher, Derek, Light, Mark E., Linclau, Bruno, Brown, Richard C. D.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973092/
https://www.ncbi.nlm.nih.gov/pubmed/31593312
http://dx.doi.org/10.1002/chem.201904479