Stereoselective Csp(3)−Csp(2) Cross‐Couplings of Chiral Secondary Alkylzinc Reagents with Alkenyl and Aryl Halides

We report palladium‐catalyzed cross‐coupling reactions of chiral secondary non‐stabilized dialkylzinc reagents, prepared from readily available chiral secondary alkyl iodides, with alkenyl and aryl halides. This method provides α‐chiral alkenes and arenes with very high retention of configuration (d...

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Detalles Bibliográficos
Autores principales: Skotnitzki, Juri, Kremsmair, Alexander, Keefer, Daniel, Gong, Ye, de Vivie‐Riedle, Regina, Knochel, Paul
Formato: Online Artículo Texto
Lenguaje:English
Publicado: John Wiley and Sons Inc. 2019
Materias:
Communications
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973128/
https://www.ncbi.nlm.nih.gov/pubmed/31529574
http://dx.doi.org/10.1002/anie.201910397

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6973128/
https://www.ncbi.nlm.nih.gov/pubmed/31529574
http://dx.doi.org/10.1002/anie.201910397

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