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CO(2)-induced single-crystal to single-crystal transformations of an interpenetrated flexible MOF explained by in situ crystallographic analysis and molecular modeling
A molecular-level investigation is reported on breathing behaviour of a metal–organic framework (1) in response to CO(2) gas pressure. High-pressure gas adsorption shows a pronounced step corresponding to a gate-opening phase transformation from a closed (1(cp)) to a large-pore (1(lp)) form. A plate...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977545/ https://www.ncbi.nlm.nih.gov/pubmed/32015814 http://dx.doi.org/10.1039/c9sc04043a |