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Role of torsional strain in the ring-opening polymerisation of low strain [n]nickelocenophanes
Ring-opening polymerisation (ROP) of strained [1]- and [2]metallocenophanes and related species is well-established, and the monomer ring-strain is manifest in a substantial tilting of the cyclopentadienyl ligands, giving α angles of ∼14–32°. Surprisingly, tetracarba[4]nickelocenophane [Ni(η(5)-C(5)...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977548/ https://www.ncbi.nlm.nih.gov/pubmed/32015807 http://dx.doi.org/10.1039/c9sc02624j |