Internal acidity scale and reactivity evaluation of chiral phosphoric acids with different 3,3′-substituents in Brønsted acid catalysis

The concept of hydrogen bonding for enhancing substrate binding and controlling selectivity and reactivity is central in catalysis. However, the properties of these key hydrogen bonds and their catalyst-dependent variations are extremely difficult to determine directly by experiments. Here, for the...

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Detalles Bibliográficos
Autores principales: Rothermel, Kerstin, Melikian, Maxime, Hioe, Johnny, Greindl, Julian, Gramüller, Johannes, Žabka, Matej, Sorgenfrei, Nils, Hausler, Thomas, Morana, Fabio, Gschwind, Ruth M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977555/
https://www.ncbi.nlm.nih.gov/pubmed/32015815
http://dx.doi.org/10.1039/c9sc02342a

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977555/
https://www.ncbi.nlm.nih.gov/pubmed/32015815
http://dx.doi.org/10.1039/c9sc02342a

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