Selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes and methylamines from cyclic amines and CO(2)/H(2) catalyzed by an ionic liquid–Pd/C system

The reduction of CO(2) with amines and H(2) generally produces N-formylated or N-methylated compounds over different catalysts. Herein, we report the selective synthesis of formamides, 1,2-bis(N-heterocyclic)ethanes, and methylamines, which is achieved over an ionic liquid (IL, e.g., 1-butyl-3-methy...

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Detalles Bibliográficos
Autores principales: Li, Ruipeng, Zhao, Yanfei, Wang, Huan, Xiang, Junfeng, Wu, Yunyan, Yu, Bo, Han, Buxing, Liu, Zhimin
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Chemistry
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977556/
https://www.ncbi.nlm.nih.gov/pubmed/32015804
http://dx.doi.org/10.1039/c9sc03242h

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6977556/
https://www.ncbi.nlm.nih.gov/pubmed/32015804
http://dx.doi.org/10.1039/c9sc03242h

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