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Enantioselective carbene insertion into the N–H bond of benzophenone imine
Efficient enantioselective insertion of α-diazoesters into the N–H bond of N-sp(2)-hybridized benzophenone imine was realized by using Rh(2)(esp)(2) and chiral guanidine cooperative catalysis. Both aliphatic and aromatic substituted α-amino esters were obtained in high yields (up to 99%) and good en...
| Autores principales: | , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979361/ https://www.ncbi.nlm.nih.gov/pubmed/32110317 http://dx.doi.org/10.1039/c9sc03354h |