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Diastereoselective ring opening of fully-substituted cyclopropanes via intramolecular Friedel–Crafts alkylation

We herein disclose a diastereoselective ring opening of non-donor–acceptor cyclopropanes via an intramolecular Friedel–Crafts alkylation en route to functionalized dihydronaphthalene scaffolds possessing quaternary carbon stereocentres. The transformation proceeds through a selective bond breaking a...

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Detalles Bibliográficos
Autores principales: Lanke, Veeranjaneyulu, Zhang, Fa-Guang, Kaushansky, Alexander, Marek, Ilan
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Royal Society of Chemistry 2019
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979362/
https://www.ncbi.nlm.nih.gov/pubmed/32055326
http://dx.doi.org/10.1039/c9sc03832a