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Determination of (2)H KIEs from Competition Experiments: Increased Accuracy via Isotopic Enrichment

Methods for the determination of (2)H KIEs at natural abundance of deuterium have not been widely used due to the requirement for very long NMR times or large reaction scale. We previously reported a simple methodology for reducing these restrictions by the addition of a small amount of deuterated s...

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Detalles Bibliográficos
Autores principales: Colletto, Chiara, Whitaker, Daniel, Larrosa, Igor
Formato: Online Artículo Texto
Lenguaje:English
Publicado: Springer US 2017
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979694/
https://www.ncbi.nlm.nih.gov/pubmed/32025177
http://dx.doi.org/10.1007/s11244-017-0740-1