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Determination of (2)H KIEs from Competition Experiments: Increased Accuracy via Isotopic Enrichment
Methods for the determination of (2)H KIEs at natural abundance of deuterium have not been widely used due to the requirement for very long NMR times or large reaction scale. We previously reported a simple methodology for reducing these restrictions by the addition of a small amount of deuterated s...
Autores principales: | Colletto, Chiara, Whitaker, Daniel, Larrosa, Igor |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
Springer US
2017
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6979694/ https://www.ncbi.nlm.nih.gov/pubmed/32025177 http://dx.doi.org/10.1007/s11244-017-0740-1 |
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