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Unconventional two-step spin relaxation dynamics of [Re(CO)(3)(im)(phen)](+) in aqueous solution
Changes of molecular spin are ubiquitous in chemistry and biology. Among spin flip processes, one of the fastest is intersystem crossing (ISC) in transition metal complexes. Here, we investigate the spin relaxation dynamics and emission spectrum of [Re(CO)(3)(im)(phen)](+) (im = imidazole, phen = ph...
| Autores principales: | , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
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Royal Society of Chemistry
2019
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| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6988600/ https://www.ncbi.nlm.nih.gov/pubmed/32110331 http://dx.doi.org/10.1039/c9sc03671g |