Silylation of Pyridine, Picolines, and Quinoline with a Zinc Catalyst

[Image: see text] Zn(OTf)(2) (OTf(–) = trifluoromethanesulfonate) catalyzes the silylation of pyridine, 3-picoline, and quinoline to afford the silylated products, where the silyl groups are meta to the nitrogen. The isolated yields of the products range from 41 to 26%. The 2- and 4-picolines yielde...

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Detalles Bibliográficos
Autores principales: Prybil, Joshua W., Wallace, Rodney, Warren, Alexandra, Klingman, Jordan, Vaillant, Romane, Hall, Michael B., Yang, Xin, Brennessel, William W., Chin, Robert M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: American Chemical Society 2020
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6990635/
https://www.ncbi.nlm.nih.gov/pubmed/32010826
http://dx.doi.org/10.1021/acsomega.9b03317

Internet

https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6990635/
https://www.ncbi.nlm.nih.gov/pubmed/32010826
http://dx.doi.org/10.1021/acsomega.9b03317

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