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Silylation of Pyridine, Picolines, and Quinoline with a Zinc Catalyst
[Image: see text] Zn(OTf)(2) (OTf(–) = trifluoromethanesulfonate) catalyzes the silylation of pyridine, 3-picoline, and quinoline to afford the silylated products, where the silyl groups are meta to the nitrogen. The isolated yields of the products range from 41 to 26%. The 2- and 4-picolines yielde...
Autores principales: | Prybil, Joshua W., Wallace, Rodney, Warren, Alexandra, Klingman, Jordan, Vaillant, Romane, Hall, Michael B., Yang, Xin, Brennessel, William W., Chin, Robert M. |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
American Chemical Society
2020
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Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6990635/ https://www.ncbi.nlm.nih.gov/pubmed/32010826 http://dx.doi.org/10.1021/acsomega.9b03317 |
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