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Caesium fluoride-mediated hydrocarboxylation of alkenes and allenes: scope and mechanistic insights
A caesium fluoride-mediated hydrocarboxylation of olefins is disclosed that does not rely on precious transition metal catalysts and ligands. The reaction occurs at atmospheric pressures of CO(2) in the presence of 9-BBN as a stoichiometric reductant. Stilbenes, β-substituted styrenes and allenes co...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
Royal Society of Chemistry
2019
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC6991174/ https://www.ncbi.nlm.nih.gov/pubmed/32055361 http://dx.doi.org/10.1039/c9sc02467k |